Living polymerization of 1-chloro-1-alkynes by MoOCl4-n-Bu4Sn-EtOH catalyst
β Scribed by Masuda, Toshio; Yoshimura, Toshio; Higashimura, Toshinobu
- Book ID
- 126495092
- Publisher
- American Chemical Society
- Year
- 1989
- Tongue
- English
- Weight
- 438 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0024-9297
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π SIMILAR VOLUMES
The polymerization of aliphatic disubstituted acetylenes was examined with MoOCl 4 -n-Bu 4 Sn-EtOH (1/1/2) ternary catalyst in anisole at 0 Β°C. Various linear aliphatic disubstituted acetylenes such as 2-nonyne provided polymers with narrow molecular weight distributions (weight-average molecular we
## Ε½ . Several organometallic compounds were examined as second catalyst components cocatalysts of the MoOCl -cocata-4 ## Ε½ . lyst -EtOH system with the motivation of development of novel catalysts for the living polymerization of substituted acetylenes. Catalyst systems such as MoOCl -Et Zn-Et