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Synthesis of acis-rich, living poly[(o-methylphenyl)acetylene] by use of the MoOCl4-n-Bu4Sn-EtOH catalyst

✍ Scribed by Hisayasu Kaneshiro; Toshio Masuda; Toshinobu Higashimura


Publisher
Springer
Year
1995
Tongue
English
Weight
299 KB
Volume
35
Category
Article
ISSN
0170-0839

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Polymerization of aliphatic disubstitute
✍ Hideki Kubo; Shigetaka Hayano; Toshio Masuda πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 119 KB

The polymerization of aliphatic disubstituted acetylenes was examined with MoOCl 4 -n-Bu 4 Sn-EtOH (1/1/2) ternary catalyst in anisole at 0 Β°C. Various linear aliphatic disubstituted acetylenes such as 2-nonyne provided polymers with narrow molecular weight distributions (weight-average molecular we