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“Living” Free-Radical Polymerizations in the Absence of Initiators: Controlled Autopolymerization

✍ Scribed by Devonport, Wayne; Michalak, Lora; Malmström, Eva; Mate, Mathew; Kurdi, Bulent; Hawker, Craig J.; Barclay, George G.; Sinta, Roger

Book ID
118134399
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
158 KB
Volume
30
Category
Article
ISSN
0024-9297

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The stable nitroxide TEMPO is shown to react with styrene and polystyrene models under conditions typically used for polymerizations. These results show that the nitroxide is not inert at the elevated temperatures necessary to conduct polymerizations. The implications of hydrogen abstraction and ole