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Acceleration in nitroxide mediated ‘living’ free radical polymerizations

✍ Scribed by Harth, Eva; Van Horn, Brooke; Hawker, Craig J.

Book ID
120007573
Publisher
Royal Society of Chemistry
Year
2001
Tongue
English
Weight
78 KB
Volume
9
Category
Article
ISSN
1359-7345

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## Abstract **Summary:** The controlled/living radical polymerizations of methyl acrylate in 50% v/v of an ionic liquid initiated by the alkoxyamine generated in situ from 4‐oxo‐2,2,6,6‐tetramethyl‐1‐piperidinyl‐__N__‐oxyl (4‐oxo‐TEMPO) and 2,2′‐azoisobutyronitrile (AIBN) at 140–155 °C are reported

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