## Abstract The paper describes the living anionic polymerization of styrenes to homoโ and diblock copolymers in continuous flow, using a microstructured mixing setโup (โmicroreactorโ). Reaction times and experimental effort are significantly reduced compared to classical batch methods that often r
Living anionic polymerization using a microfluidic reactor
โ Scribed by Iida, Kazunori ;Chastek, Thomas Q. ;Beers, Kathryn L. ;Cavicchi, Kevin A. ;Chun, Jaehun ;Fasolka, Michael J.
- Book ID
- 118224812
- Publisher
- Royal Society of Chemistry
- Year
- 2009
- Tongue
- English
- Weight
- 657 KB
- Volume
- 9
- Category
- Article
- ISSN
- 1473-0197
- DOI
- 10.1039/b810006c
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A modular high-vacuum system for large-scale anionic polymerization reactions was designed that utilizes mechanical agitation in place of magnetic stirring, Teflon Rotoflo stopcocks in place of glass breakseals, and spherical o-ring joints in place of direct glass seals. A standard reactor body was