Anionic living polymerization of functionalized monomers
β Scribed by A. Hirao; S. Nakahama
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 139 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0323-7648
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The anionic polymerization of allyl methacrylate was carried out in tetrahydrofuran, both in the presence and in the absence of LiCl, with a variety of initiators, at various temperatures. It was found that (1,1-diphenylhexyl)lithium and the living oligomers of methyl methacrylate and tert-butyl met
The anionic polymerization of tBMA initiated by an organolithium compound in toluene at low temperature (Γ78 Β°C and 0 Β°C) has been revisited. Under these experimental conditions, no `livingness' is reported, consistently with formation of an important fraction of oligomers (M n = 650).