Living Anionic Polymerization of Phosphorus-Bridged [1]Ferrocenophanes: Synthesis and Characterization of Well-Defined Poly(ferrocenylphosphine) Homopolymers and Block Copolymers
β Scribed by Peckham, Timothy J.; Massey, Jason A.; Honeyman, Charles H.; Manners, Ian
- Book ID
- 120446285
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 166 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0024-9297
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π SIMILAR VOLUMES
## Abstract Wellβdefined poly(ferrocenyldimethylgermane) homopolymers PFDMG [$\overline M \_{\rm n} $β=β18β800β33β700, degree of polymerization ($\overline {DP} \_{\rm n} $)β=β66β117, polydispersity index (PDI)β=β1.02β1.05] and polyisopreneβ__block__βpoly(ferrocenyldimethylgermane) diblock copolyme
Photocontrolled living anionic ring-opening polymerization (ROP) of strained silicon-bridged [1] 3) with 3,3,3-trifluoropropyl, heptadecafluoro-1,1,2,2-tetrahydrodecyl, and pentafluorophenylpropyl hydrofluorocarbon substituents, respectively, on silicon, have been explored. Thus well-defined fluorin