## Abstract The ring‐opening polymerization (ROP) behavior of a variety of substituted 1,1′‐ethylenylferrocenes, or dicarba[2]ferrocenophanes, is reported. The electronic absorption spectra and tilted solid‐state structures of the monomers __rac__‐[Fe(η^5^‐C~5~H~4~)~2~(CH__i__Pr)~2~] (7), [Fe(η^5^‐
Photocontrolled Living Anionic Polymerization of Phosphorus-Bridged [1]Ferrocenophanes: A Route to Well-Defined Polyferrocenylphosphine (PFP) Homopolymers and Block Copolymers
✍ Scribed by Sanjib K. Patra; George R. Whittell; Simone Nagiah; Cheuk-Lam Ho; Wai-Yeung Wong; Ian Manners
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 470 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0947-6539
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Photocontrolled living anionic ring-opening polymerization (ROP) of strained silicon-bridged [1] 3) with 3,3,3-trifluoropropyl, heptadecafluoro-1,1,2,2-tetrahydrodecyl, and pentafluorophenylpropyl hydrofluorocarbon substituents, respectively, on silicon, have been explored. Thus well-defined fluorin
## Abstract Well‐defined poly(ferrocenyldimethylgermane) homopolymers PFDMG [$\overline M \_{\rm n} $ = 18 800–33 700, degree of polymerization ($\overline {DP} \_{\rm n} $) = 66–117, polydispersity index (PDI) = 1.02–1.05] and polyisoprene‐__block__‐poly(ferrocenyldimethylgermane) diblock copolyme