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Lithium triethoxyaluminohydride as a convenient reagent for the conversion of nitriles to aldehydes

โœ Scribed by Herbert C. Brown; Charles J. Shoaf; C.P. Garg

Publisher
Elsevier Science
Year
1959
Tongue
French
Weight
136 KB
Volume
1
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES

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Diphenylphosphinodithioic acid is a reagent useful for a sequence effecting the hydrolysis of nitriles under mild conditions. Of all functional groups at the acyl level of oxidation, nitriles are the most resistant to reaction. The poor electrophilicity of the carbon combined with the weak basicity

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## Vilsmeier reagents I have previously been used almost exclusively for formylation (I). More recently they were shown to be useful reagents in organic synthesis.