Mkhael acWtion of potassio-or sodioalkoxides to a-nitroolefins prvvides essentially pure /3nitroethets (l-10) in 78-100% iso&?d yiekf.
Lithium, potassium, and sodium alkoxides: donors in the Michael addition reaction of α-nitroolefins
✍ Scribed by J.L. Duffy; J.A. Kurth; M.J. Kurth
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- French
- Weight
- 686 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
CycJic $-ketoesWn and pketoamfdes am convelled to 2-(calbakoxy)-CONEt, and 2-(aminocafbonyf)-2cydoalken-lanes by treatment with Pb(OAc)4 CON& Ftl(OAc), cu(oAc)P & I and Cu(OAc)p in benzene; 89.1 + 2.
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