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Lithium perchlorate/diethyl ether catalyzed one-pot synthesis of α-hydrazinophosphonates from aldehydes by a three-component reaction

✍ Scribed by Akbar Heydari; Abdollah Javidan; Mehdi Schaffie

Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
131 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis

Various a-hydrazinophosphonates were prepared on the basis of three-component (aldehydes, N,N-dimethylhydrazine, and dimethyl(trimethylsilyl)phosphite, coupling reactions via LiClO 4 -catalyzed tandem reactions.

📜 SIMILAR VOLUMES

ChemInform Abstract: Lithium Perchlorate
ChemInform Abstract: Lithium Perchlorate/Diethyl Ether Catalyzed One-Pot Synthesis of α-Hydrazinophosphonates from Aldehydes by a Three-Component Reaction.
✍ Akbar Heydari; Abdollah Javidan; Mehdi Schaffie 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

One-pot synthesis of N-trimethylsilyloxy
One-pot synthesis of N-trimethylsilyloxy-α-amino phosphonates from aldehydes using lithium perchlorate/diethyl ether as a catalyst
✍ Akbar Heydari; Mahmoud Zarei; Reza Alijanianzadeh; Hossein Tavakol 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 75 KB

A simple and efficent one-pot method was developed to give N-trimethylsilyloxy-a-amino phosphonate derivatives from aldehydes+hydroxylamines+dimethyl(trimethylsilyl)phosphonate in lithium perchlorate/diethyl ether solution (LPDE) in high yields.