Lithium ion transport in Li2O-LiCl-CaO-B2O3 glasses
β Scribed by S.L. Shue; H.L. Tuller
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 173 KB
- Volume
- 40-41
- Category
- Article
- ISSN
- 0167-2738
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Thermal and spectroscopic studies have been carried out on a number of glasses with wide ranging compositions in the pseudoternary glass system Li 2 O+PbO+B 2 O 3 in order to understand the structural role of PbO in these glasses. Infrared, Raman, and 11 B MAS-NMR results indicate that PbO behaves a
Experimental data are presented for the variation with temperature and composition of a lithium borate glass doped with Li2SO 4. A statistical mechanical theory of conductivity is developed based on the assumption that Li20 and Li2SO 4 behave as weak electrolytes which dissociate to provide free Li