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Lithium bromide catalyzed homologation of aldehydes with aryldiazomethanes

โœ Scribed by Loeschorn, Carol A.; Nakajima, Masayuki; McCloskey, Patrick J.; Anselme, Jean Pierre


Book ID
120073146
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
614 KB
Volume
48
Category
Article
ISSN
0022-3263

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Aliphatic linear and a-branched aldehydes efficiently undergo arylation at the a-position upon treatment with aryl bromides using an appropriate palladium catalyst system that is capable of overcoming aldol condensation of the substrates.