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Lithium aluminum hydride on silica gel - selective reduction of ketones and carboxy esters in the presence of nitro and cyano groups

✍ Scribed by Yasuhiro Kamitori; Masaru Hojo; Ryōichi Masuda; Tatsuro Inoue; Tatsuo Izumi

Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
133 KB
Volume
24
Category
Article
ISSN
0040-4039

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✦ Synopsis

Cyano and nitro groups were found not to be reduced by Zithiwn alwninwn hydride on silica gel and with the use of this reagent ketones and carboxy esters bearing cyano and nitro groups were successfuZZy converted into the corresponding cyano and nitro alcohols.

📜 SIMILAR VOLUMES

Selective reduction of ketoesters to hyd
Selective reduction of ketoesters to hydroxyesters with the use of lithium aluminum hydride in the presence of silica gel
✍ Yasuhiro Kamitori; Masaru Hojo; Ryōichi Masuda; Tatsuro Inoue; Tatsuo Izumi 📂 Article 📅 1982 🏛 Elsevier Science 🌐 French ⚖ 222 KB

Lithium aluminum hydride, in the presence of a small amount of silica gel, has been found to be a versatile and highly selective reagent for reduction of various ketoesters to the corresponding hydroxyesters in fair yields. Recently we reported a series of new synthetic reactions l-7) with the use