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Lithium Acetate-Catalyzed Crossed Aldol Reaction Between Aldehydes and Trimethylsilyl Enolates Generated from Other Aldehydes.

✍ Scribed by Yoshikazu Kawano; Hidehiko Fujisawa; Teruaki Mukaiyama

Publisher
John Wiley and Sons
Year
2005
Weight
23 KB
Volume
36
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES

Product-Catalyzed Aldol Reaction between
Product-Catalyzed Aldol Reaction between Trimethylsilyl Enolates and Aldehydes
✍ Hidehiko Fujisawa; Takashi Nakagawa; Teruaki Mukaiyama πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 240 KB

## Abstract Aldol reactions between trimethylsilyl ketene acetals and aldehydes by using a catalytic amount of alkoxide anion proceeded smoothly to afford the corresponding aldols in DMF, indicating that the initially‐formed aldolate anion effectively worked to catalyze the reaction. The β€œproduct‐c