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Lithium Acetate-Catalyzed Aldol Reaction Between Aldehyde and Trimethylsilyl Enolate.

✍ Scribed by Takashi Nakagawa; Hidehiko Fujisawa; Teruaki Mukaiyama

Publisher
John Wiley and Sons
Year
2003
Weight
108 KB
Volume
34
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES

Product-Catalyzed Aldol Reaction between
Product-Catalyzed Aldol Reaction between Trimethylsilyl Enolates and Aldehydes
✍ Hidehiko Fujisawa; Takashi Nakagawa; Teruaki Mukaiyama πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 240 KB

## Abstract Aldol reactions between trimethylsilyl ketene acetals and aldehydes by using a catalytic amount of alkoxide anion proceeded smoothly to afford the corresponding aldols in DMF, indicating that the initially‐formed aldolate anion effectively worked to catalyze the reaction. The β€œproduct‐c