Lithiophosphinoferrocenes. A route to polyphosphines and ring-substituted ferrocenophanes
✍ Scribed by Butler, Ian R.; Cullen, William R.
- Book ID
- 126267453
- Publisher
- American Chemical Society
- Year
- 1986
- Tongue
- English
- Weight
- 859 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0276-7333
No coin nor oath required. For personal study only.
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## Abstract The ring‐opening reactions of a series of sila[1]ferrocenophanes with protic acids of anions with various degrees of noncoordinating character have been explored. Ferrocenyl‐substituted silyl triflates FcSiMe~2~OTf (5 a) and Fc~3~SiOTf (5 b) (Fc=(η^5^‐C~5~H~4~)Fe(η^5^‐C~5~H~5~)) were sy
## Abstract The ring‐opening polymerization (ROP) behavior of a variety of substituted 1,1′‐ethylenylferrocenes, or dicarba[2]ferrocenophanes, is reported. The electronic absorption spectra and tilted solid‐state structures of the monomers __rac__‐[Fe(η^5^‐C~5~H~4~)~2~(CH__i__Pr)~2~] (7), [Fe(η^5^‐