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Ring-opening polymerization of strained, ring-tilted ferrocenophanes: a route to high-molecular-weight poly(ferrocenylsilanes)

✍ Scribed by Foucher, Daniel A.; Tang, Ben Zhong; Manners, Ian


Book ID
127065524
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
934 KB
Volume
114
Category
Article
ISSN
0002-7863

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## Abstract The transition metal‐catalyzed ring‐opening polymerization of dimethyl[1]silaferrocenophane (fcSiMe~2~) (1), fc = Fe(__η__‐C~5~H~4~)~2~), in the presence of MePhSiH~2~, or the chlorosilanes ClMe~2~SiH, ClMePhSiH, or ClPh~2~SiH has been shown to allow access to poly(ferrocenylsilane)s R^