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Lithiation of heterocycles directed by .alpha.-amino alkoxides

โœ Scribed by Comins, Daniel L.; Killpack, Michael O.


Book ID
120200597
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
812 KB
Volume
52
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES


N-methyl lithiation of N-methylindoles d
โœ Daniel L. Comins; Michael O. Killpack ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 200 KB

A novel N-methyl lithiafion-alkylation of an a-amino alkoxide derived from 3-chloro-Nmethylindole-Z-carboxaldehyde is described. The reaction of aromatic aldehydes with certain lithium dialkylamides gives a-amino alkoxides in situ that can be ring lithiated with alkyllithiums. Alkylation and hydrol

Lithiation Directed by Amino Alkoxides.
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