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Liquid-phase chlorination ofC-chlorovinylsilanes

✍ Scribed by V. G. Lakhtin; V. L. Ryabkov; A. V. Kisin; V. M. Nosova; M. V. Polyakova; E. A. Chernyshev


Book ID
112386644
Publisher
Springer
Year
1995
Tongue
English
Weight
460 KB
Volume
44
Category
Article
ISSN
1573-9171

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T h e rate constants of liquid-phase hydrogen abstraction by chlorine atoms from 1,2-CzH&12 relative to those of addition to CzHClB and to C&14 and to that of hydrogen abstraction from cyclohexane have been measured between 250 and 345Β°K. Assuming a zero activation energy for the addition reactions