Liquid-phase chlorination ofC-chlorovinylsilanes
β Scribed by V. G. Lakhtin; V. L. Ryabkov; A. V. Kisin; V. M. Nosova; M. V. Polyakova; E. A. Chernyshev
- Book ID
- 112386644
- Publisher
- Springer
- Year
- 1995
- Tongue
- English
- Weight
- 460 KB
- Volume
- 44
- Category
- Article
- ISSN
- 1573-9171
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## Abstract The hydrogen abstraction from the chlorinated ethanes by chlorine atoms has been investigated in the liquid phase. Rate constants relative to that for hydrogen abstraction from chloroform have been measured between 267Β° and 333Β°K using a competition technique. The results are compared w
T h e rate constants of liquid-phase hydrogen abstraction by chlorine atoms from 1,2-CzH&12 relative to those of addition to CzHClB and to C&14 and to that of hydrogen abstraction from cyclohexane have been measured between 250 and 345Β°K. Assuming a zero activation energy for the addition reactions