Liquid injection field desorption/ionization of reactive transition metal complexes
✍ Scribed by Jürgen H. Gross; Norbert Nieth; H. Bernhard Linden; Ulrike Blumbach; Frank J. Richter; Michael E. Tauchert; Rolf Tompers; Peter Hofmann
- Book ID
- 105890148
- Publisher
- Springer
- Year
- 2006
- Tongue
- English
- Weight
- 223 KB
- Volume
- 386
- Category
- Article
- ISSN
- 1618-2650
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📜 SIMILAR VOLUMES
## Abstract Field desorption mass spectrometry was used to obtain molecular weight information on a variety of transition metal complexes which are air sensitive and nonvolatile. The base peak for the neutral complexes is the molecular ion and for the salt complexes is the cation.
Transition metal ion complexes with proteins and peptides are important in many areas of analytical and biological chemistry. We used positive and negative ion MALDI-MS to detect complexes with Cu and Ni ions, and show that the speciÐc and non-speciÐc transition metal ion-peptide complexes can be di