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Lipase-mediated esterification of racemic alcohols: A comparison of 2-substituted cyclohexanols and cyclopentanols

✍ Scribed by Marie Zarevúcka; Martin Rejzek; Zdeněk Wimmer; Jan Zima; Qiu-yu Zhao; Marie-Dominique Legoy


Book ID
104656603
Publisher
Springer Netherlands
Year
1995
Tongue
English
Weight
240 KB
Volume
17
Category
Article
ISSN
0141-5492

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✦ Synopsis


Esterification of five-and six-membered-ring-containing alcohols catalysed by three different lipases (those from porcine pancreas, Candida cylindracea and Geotrichum candidum) was studied. Some conversions gave high stereochemical purity, but all gave low yields.


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ChemInform Abstract: Lipase-Mediated Dia
✍ R. TANIKAGA; A. MORITA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 1 views

Lipase-Mediated Diastereoselective and Enantioselective Acetylations of 3-Substituted Cyclohexanols. -Lipase-mediated acetylation of a diastereomeric mixture of 3-substituted cyclohexanols (II)/(III) results in efficient resolution providing the acetates (V) in high enantiomeric excess. -