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Lipase kinetics in organic-water solvent with amphipathic substrate for chiral reaction

✍ Scribed by Satish C. Mohapatra; James T. Hsu

Book ID
111697432
Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
261 KB
Volume
55
Category
Article
ISSN
0006-3592

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Scandium trisdodecylsulfate (STDS). A ne
Scandium trisdodecylsulfate (STDS). A new type of lewis acid that forms stable dispersion systems with organic substrates in water and accelerates aldol reactions much faster in water than in organic solvents
✍ ShΕ« Kobayashi; Takeshi Wakabayashi πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 French βš– 297 KB

A new type of Lewis acid, scandium trisdodecylsulfate (STDS), was prepared. In the presence of a catalytic amount of STDS, aldol reactions of silyl enol ethers with aldehydes proceeded smoothly in water without using any organic solvents. It was proven that stable dispersion systems including the ca