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Lipase-catalyzed irreversible transesterification using enol esters: resolution of prostaglandin synthons 4-hydroxy-2-alkyl-2-cyclopentenones and inversion of the 4S enantiomer to the 4R enantiomer

✍ Scribed by Babiak, Kevin A.; Ng, John S.; Dygos, John H.; Weyker, Cara L.; Wang, Yi Fong; Wong, Chi Huey

Book ID
121185212
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
757 KB
Volume
55
Category
Article
ISSN
0022-3263

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📜 SIMILAR VOLUMES

Lipase-catalyzed irreversible transester
Lipase-catalyzed irreversible transesterification using enol esters: Resolution of cyanohydrins and syntheses of ethyl (R)-2-hydroxy-4-phenylbutyrate and (S)-propranolol
✍ Yi-Fong Wang; Shui-Tein Chen; Kevin K.-C. Liu; Chi-Huey Wong 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 253 KB

Procedures for the resolution of several cyanohydrins of synthetic value via lipase-catalyzed kinetic resolution using enol esters as irreversible transesterification reagents are developed and the syntheses of ethyl (R)-2-hydroxy-4-phenylbutyrate and (S)-propranolol from enantiomerically pure cyano