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Lipase-catalyzed esterification of 2-monoricinolein for 1,2(2,3)-diricinolein synthesis

✍ Scribed by Charlotta Turner; Seiji Wani; Rosalind Wong; Jiann-Tsyh Lin; Thomas McKeon


Book ID
107487754
Publisher
Springer-Verlag
Year
2006
Tongue
English
Weight
280 KB
Volume
41
Category
Article
ISSN
0024-4201

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The hydroxyl group at C‐5 in racemic 1,2‐__O__‐Cyclohexylidene‐__myo__‐inositol (__rac__‐1) was regio‐ and enantioselectively acylated to give 5‐__O__‐acetyl‐ (2a)‐ or 5‐__O__‐butyryl‐2,3‐__O__‐cyclohexylidene‐__myo__‐inositol (3a), respectively, by treatment of 1 with vinyl acetate or 2,2,2‐trifluo