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Lipase-catalyzed alcoholysis with supercritical carbon dioxide extraction 1: Influence of flow rate

✍ Scribed by Helga Gunnlaugsdottir; Björn Sivik

Book ID
107495184
Publisher
Springer-Verlag
Year
1997
Tongue
English
Weight
179 KB
Volume
74
Category
Article
ISSN
0003-021X

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In lipase-catalyzed asymmetrization of 1,3-propanediacetate no enantioselectivity was observed in conventional organic solvents, whereas in supercritical carbon dioxide (scCO 2 ) enantioselectivities were observed up to 50% ee, which probably arose from a conformational changing of lipase at the act