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Lipase catalysed resolution of nitro aldol adducts

✍ Scribed by Menno J Sorgedrager; Rita Malpique; Fred van Rantwijk; Roger A Sheldon

Book ID
108283746
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
262 KB
Volume
15
Category
Article
ISSN
0957-4166

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## Abstract An effective kinetic resolution of hydroxymethylchromanes racemic **2a** and **3a** has been achieved by means of enantioselective transesterification with vinyl acetate in organic solvents. The alcohols (‐)‐__R__‐**2a** and (‐)‐__S__‐**3a** were obtained with high optical purities (94