Linear, Redox-Active Pt6 and Pt2Pd2Pt2 Clusters
✍ Scribed by Eri Goto; Rowshan A. Begum; Shuzhong Zhan; Tomoaki Tanase; Katsumi Tanigaki; Ken Sakai
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 215 KB
- Volume
- 116
- Category
- Article
- ISSN
- 0044-8249
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## Abstract Sol‐gel synthesis of silica and silica–tantalum oxide embedded platinum nanoparticles is carried out using Pt colloids as templates. These colloids are prepared by reduction with Na[AlEt~3~H] and stabilized with different ligands (ammonium halide derivatives, non‐ionic surfactants with
## Abstract Pentanuclear linear‐chain PtPd complexes {[Pt~2~(NH~3~)~2~X~2~(μ‐pivalamidato)~2~(CH~2~COCH~3~)]~2~[PdX′~4~]}·2CH~3~COCH~3~ (X = X′ = Cl (1a), X = Cl, X′ = Br (1b), X = Br, X′ = Cl (1c), X = X′ = Br (1d)) composed of a monomeric Pd^II^ complex sandwiched by two amidato‐bridged dimeric P