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Linear, Redox-Active Pt6 and Pt2Pd2Pt2 Clusters

✍ Scribed by Eri Goto; Rowshan A. Begum; Shuzhong Zhan; Tomoaki Tanase; Katsumi Tanigaki; Ken Sakai


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
215 KB
Volume
116
Category
Article
ISSN
0044-8249

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Linear, Redox-Active Pt6 and Pt2Pd2Pt2 C
✍ Eri Goto; Rowshan A. Begum; Shuzhong Zhan; Tomoaki Tanase; Katsumi Tanigaki; Ken 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 216 KB
Mesoporous Pt–SiO2 and Pt–SiO2–Ta2O5 Cat
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## Abstract Sol‐gel synthesis of silica and silica–tantalum oxide embedded platinum nanoparticles is carried out using Pt colloids as templates. These colloids are prepared by reduction with Na[AlEt~3~H] and stabilized with different ligands (ammonium halide derivatives, non‐ionic surfactants with

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## Abstract Pentanuclear linear‐chain PtPd complexes {[Pt~2~(NH~3~)~2~X~2~(μ‐pivalamidato)~2~(CH~2~COCH~3~)]~2~[PdX′~4~]}·2CH~3~COCH~3~ (X = X′ = Cl (1a), X = Cl, X′ = Br (1b), X = Br, X′ = Cl (1c), X = X′ = Br (1d)) composed of a monomeric Pd^II^ complex sandwiched by two amidato‐bridged dimeric P