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Pt-Dumbbells in Ba3Pt2: Interplay of Geometric and Relativistic Effects on Pt—Pt Bonding.

✍ Scribed by Andrey Karpov; Ulrich Wedig; Martin Jansen


Publisher
John Wiley and Sons
Year
2005
Weight
10 KB
Volume
36
Category
Article
ISSN
0931-7597

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Binuclear Hydridoplatinum(II): One-Pot S
✍ Anna Laura Bandini; Guido Banditelli; Mario Manassero; Alberto Albinati; Daniele 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 193 KB

## Abstract The binuclear platinum(II) hydride [Pt~2~(dcype)~2~(H)~3~][Cl] (1b) has been isolated in high yields by treatment of Pt(dcype)Cl~2~ with NaBH~4~ (molar ratio 1:2) in ethanol solution at room temperature. This one‐pot synthesis is not straightforward when starting from diphenylphosphanyl