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Linear magnetic dichroism in fluorescence spectra

✍ Scribed by A.N. Grum-Grzhimailo; N.M. Kabachnik


Book ID
104337961
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
92 KB
Volume
264
Category
Article
ISSN
0375-9601

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✦ Synopsis


We discuss possible linear magnetic dichroism effects in fluorescence radiation following photoionization by linearly polarized light in the inner shell of oriented andror aligned atoms. A general expression for the fluorescence dichroism is presented and analysed for particular kinematical conditions. Simple dynamical predictions are made for a particular case of LSJ-coupling.


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T h c magnetic circular dichroism spectra of a numbcr of indolc alkaloids show two B-tcrms of opposite sign in thc 250-330 nni wavelength region associated with the l L b and lL, clectronic transitions, thc long ivavelength, lLt,, band being of positive sign, whereas both bands strongly ovcrlap in a