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Linear free energy relations for predicting dissolution rates of solids

✍ Scribed by Sverjensky, Dimitri A.

Book ID
109781215
Publisher
Nature Publishing Group
Year
1992
Tongue
English
Weight
378 KB
Volume
358
Category
Article
ISSN
0028-0836

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Kinetic experiments on proton dtscharge at mercury over a range of temperature show that an important entropy component arises in the linear free-energy relationship for the electrode kmetics, m addition to the potential dependence of the Fermi level. The entropy effect is attributed to the potentt