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Linear free energy correlation of the half-wave potentials of some substituted N-aroyl-N′-phenyl diimides and N-benzoyl-N′-aryl diimides

✍ Scribed by John T. Larkins; Henry Evans; Jesse M. Nicholson

Book ID
104249369
Publisher
Elsevier Science
Year
1970
Tongue
French
Weight
214 KB
Volume
11
Category
Article
ISSN
0040-4039

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✦ Synopsis

We wish to report the polarographic study of two series of disubstituted diimides in 70% AQUEOUS ETHANOL WITH O.&N potassium chloride as supporting electrolyte at 30.0°C(*). See Table I.

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The kinetics and linear free energy corr
The kinetics and linear free energy correlation of the alcoholyses of some N-aroyl-N′-phenyl diimides and N-benzoyl-N′-aryl diimides
✍ Theophile Carty; Jesse M. Nicholson 📂 Article 📅 1970 🏛 Elsevier Science 🌐 French ⚖ 141 KB

A few years ago, we reported that the alcoholysis of N-BenoyI-N'-phenyldiimide led to the (21 formation of phenyl radicals. Thus this reaction sequence was indeed unique, since it was a heterolysis, which was followed by a homolysis in a polar media.