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Linear free energy and reactivity-selectivity relationships in reactions of diarylcarbenium ions with .pi.-nucleophiles

✍ Scribed by Mayr, Herbert; Schneider, Reinhard; Grabis, Ute


Book ID
125985372
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
924 KB
Volume
112
Category
Article
ISSN
0002-7863

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It is noted that the "reactivity-selectivity" and the "constant selectivity" relationships for the R+ + Nu reactions can coexist if diffusion-controlled rates for one nucleophile govern the behaviour at the reactivity-selectivity region. RELATIONSHIPS IN REACTIONS OF CARBONIUM IONS WITH NUCLEOPHILE