On the coexistence of the “reactivity-selectivity” and the “constant selectivity” relationships in reactions of carbonium ions with nucleophiles

✍ Scribed by Zvi Rappoport

• Publisher: Elsevier Science
• Year: 1979
• Tongue: French
• Weight: 292 KB
• Volume: 20
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(01)86348-6

✦ Synopsis

It is noted that the "reactivity-selectivity" and the "constant selectivity" relationships for the R+ + Nu reactions can coexist if diffusion-controlled rates for one nucleophile govern the behaviour at the reactivity-selectivity region.

RELATIONSHIPS IN REACTIONS OF CARBONIUM IONS WITH NUCLEOPHILES