Absolute line intensities for the n 9 fundamental ( 458.228 cm 01 ) in HNO 3 were determined for the first time, using tunable diode laser spectroscopy. This technique permitted short integration times, proven important to avoid dissociation in this highly reactive species. Thirty-eight transitions
Line Intensities in the ν8Band of HNO3
✍ Scribed by W.F. Wang; E.C. Looi; T.L. Tan; P.P. Ong
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 657 KB
- Volume
- 178
- Category
- Article
- ISSN
- 0022-2852
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✦ Synopsis
Line intensity measurements have been made on the n 8 band of HNO 3 using a high-resolution Fourier transform infrared spectrum in the region 739-800 cm 01 . A least-squares fit of a total of 710 line intensities in the P and R branches was performed, leading to accurate determination of five dipole moment operator constants. By utilizing these constants, the observed line intensities are well reproduced with an average random error of 6% and the integrated band intensity is found to be 15.7 { 0.9 cm 02 atm 01 at 296 K.
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