Limiting ionic partial molar volumes of R4N+ and Br− in aqueous ethanol at 298.15 K
✍ Scribed by P.S. Nikam; T.B. Pawar; A.B. Sawant; Mehdi Hasan
- Publisher
- Elsevier Science
- Year
- 2006
- Tongue
- English
- Weight
- 101 KB
- Volume
- 126
- Category
- Article
- ISSN
- 0167-7322
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✦ Synopsis
The densities of tetraalkyl ammonium bromide, R 4 NBr (R=CH 3 through n-C 4 H 9 ), NaBPh 4 and NaBr solutions in (0, 10, 30, 50, 70, 90, and 100) mass% ethanol+water have been measured over the whole composition range at 298.15 K. From the densities, apparent and limiting partial molar volumes of the electrolytes and ions in these mixtures have been evaluated.
📜 SIMILAR VOLUMES
The results of excess molar volumes for the ternary mixture N, N-dimethylformamide Ž . 4 Ž . Ž DMF q ethanol q water , and for the binary constituents DMF q water , DMF q . Ž . ethanol , and ethanol q water at T s 298.15 K were reported. Several empirical expressions were used to predict and correla