✦ LIBER ✦

Light-mediated oxidation of alcohols and mandelate by flavin-metal complexes

✍ Scribed by Seiji Shinkai; Hideki Nakao; Kaori Ueda; Osamu Manabe

Publisher: Elsevier Science
Year: 1984
Tongue: French
Weight: 221 KB
Volume: 25
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)81587-2

No coin nor oath required. For personal study only.

✦ Synopsis

New flavins with metal affinity, (1) and ( 2) were applied to photo-oxidation of alcohols and mandelate.

(1) rapidly photooxidized alcohols in the presente of Mg(I1) and Zn(I1): the rate augmentation corresponds to 16-18 fold. (2) could photo-oxidize PhCH(OH)COO-K+ but only slightly PhCH(OH)COO_NMe4+: the rate difference amounts to llO-fold. Thus, the photo-oxidizability of these modified flavins can be markedly improved through complexation with metal ions.

📜 SIMILAR VOLUMES

Metal-Mediated Oxidation of Tertiary Alc

Metal-Mediated Oxidation of Tertiary Alcohols and Related Fragmentations

✍ Karine Wietzerbin; Jean Bernadou; Bernard Meunier 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 969 KB

Oxidation of alcohols by transition meta

Oxidation of alcohols by transition metal complexes part V. Selective catalytic monoalkylation of arylacetonitriles by alcohols

✍ Ronald Grigg; Thomas R.B. Mitchell; Somyote Sutthivaiyakit; Ngampong Tongpenyai 📂 Article 📅 1981 🏛 Elsevier Science 🌐 French ⚖ 184 KB

Transposition of Allylic Alcohols into C

Transposition of Allylic Alcohols into Carbonyl Compounds Mediated by Transition Metal Complexes

✍ Ramalinga Uma; Christophe Crevisy; Rene Gree 📂 Article 📅 2003 🏛 John Wiley and Sons ⚖ 52 KB

## Abstract For Abstract see ChemInform Abstract in Full Text.

ChemInform Abstract: Metal-Mediated Oxid

ChemInform Abstract: Metal-Mediated Oxidation of Tertiary Alcohols and Related Fragmentations

✍ Karine Wietzerbin; Jean Bernadou; Bernard Meunier 📂 Article 📅 2000 🏛 John Wiley and Sons ⚖ 24 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

ChemInform Abstract: Oxidation and Depro

ChemInform Abstract: Oxidation and Deprotection of Primary Benzylamines by Visible Light Flavin Photocatalysis.

✍ Robert Lechner; Burkhard Koenig 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 42 KB 👁 1 views

Oxidation of alcohols by transition meta

Oxidation of alcohols by transition metal complexes—iv : The rhodium catalysed synthesis of esters from aldehydes and alcohols

✍ Ronald Grigg; Thomas R.B. Mitchell; Somyote Sutthivaiyakit 📂 Article 📅 1981 🏛 Elsevier Science 🌐 French ⚖ 646 KB