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Light-Induced Excited Spin State Trapping: Ab Initio Study of the Physics at the Molecular Level

✍ Scribed by Suaud, Nicolas; Bonnet, Marie-Laure; Boilleau, Corentin; Labèguerie, Pierre; Guihéry, Nathalie

Book ID
118118218
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
700 KB
Volume
131
Category
Article
ISSN
0002-7863

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Reversibility of light-induced excited spin state trapping in the Fe(ptz)6(BF4)2, and the Zn1−xFex(ptz)6(BF4)2 spin-crossover systems
✍ A. Hauser 📂 Article 📅 1986 🏛 Elsevier Science 🌐 English ⚖ 438 KB

Fe(ptz)6(BF4)2 (ptz = I-propyltetrazole) is an iron(H) spin-crossover system which shows light-Induced excited spin state trapping. In this paper we show that (a) the same phenomenon can also be observed in Zn, \_ rFeX(ptz)6(BF4)2 (x = 0.1) and is therefore basically a single-ion property, and (b) t