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Light-Induced [2+2] Cycloaddition Reactions of Nonconjugated Dienes—the Effect of Through-Bond Interaction

✍ Scribed by Prof. Dr. Rolf Gleiter; Dr. Wolfram Sander


Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
299 KB
Volume
24
Category
Article
ISSN
0044-8249

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Ab initio study of the effect of CH ···
✍ D. Suárez; R. López; J. González; T. L. Sordo; J. A. Sordo 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 402 KB 👁 3 views

Ab initio calcdations at the MP2/6-31G\*//HF/3-21G\* level have been carried out to study Eels-Alder reactions of 2-substituted-1,3-dienes with s u l h dioxide. The CH ... 0 electrostatic interaction detected in some of the transition structures located could be decisive in the control of the exo/en