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ChemInform Abstract: The Diene Effect: The Design, Development, and Mechanistic Investigation of Metal-Catalyzed Diene-yne, Diene-ene, and Diene-allene [2 + 2 +1] Cycloaddition Reactions.

โœ Scribed by Mitchell P. Croatt; Paul A. Wender


Publisher
John Wiley and Sons
Year
2010
Weight
16 KB
Volume
41
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Palladium-Catalyzed
โœ C. W. HOLZAPFEL; L. MARAIS ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 35 KB ๐Ÿ‘ 1 views

Palladium-Catalyzed Cyclization and Functionalization of 1,1-Diacetoxy-2,7-diene and 1,1-Diacetoxy-2-en-7-yne Derivatives. -The Pd-catalyzed metallo-ene cyclization of (I) provides cyclic enolates which can be easily transformed to aldehydes (III) amenable to further transformation. Cyclization/car