LIGHT CATALYZED ORGANIC REACTIONS. V. 1 THE ADDITION OF AROMATIC CARBONYL COMPOUNDS TO A DISUBSTITUTED ACETYLENE
✍ Scribed by Büchi, G.; Kofron, James T.; Koller, E.; Rosenthal, David
- Book ID
- 127021094
- Publisher
- American Chemical Society
- Year
- 1956
- Tongue
- English
- Weight
- 251 KB
- Volume
- 78
- Category
- Article
- ISSN
- 0002-7863
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A reasonably stabilized trichloromethyl anion (TCMA) was formed by the reaction of chloroform with an electrogenerated base prepared by the electroreduction of Zpyrrolidone, and the addition of this TCIvIA to a$unsaturated esters gave the corresponding B-trichloromethyl esters in good yields.