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ChemInform Abstract: Synthesis of Carbonyl Compounds Based on the Products of Addition of Polyhaloalkanes to Unsaturated Systems. Reactions of 1-Aryl-5,5- dichloropenta-2,4-dien-1-ones with Ethyl Acetoacetate.

✍ Scribed by S. A. VOZNESENSKII; A. A. DUDINOV; L. I. BELEN'KII; M. I. STRUCHKOVA; V. N. NESTEROV; M. M. KRAYUSHKIN; YU. T. STRUCHKOV

Publisher: John Wiley and Sons
Year: 2010
Weight: 29 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199738136

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✦ Synopsis

Synthesis of Carbonyl Compounds Based on the Products of Addition of Polyhaloalkanes to Unsaturated Systems. Reactions of 1-Aryl-5,5-dichloropenta-2,4-dien-1-ones with Ethyl Acetoacetate.

-Reaction of the pentadienones (I) with ethyl acetoacetate gives the ethyl cyclohexylcarboxylates (III) via the corresponding Michael addition products. The structure of derivative (IIIa) is studied by X-ray crystallography.

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