Ligand-Property Control in the Nickel(0)/Butadiene/P-Ligand Catalytic System: “Electronic” Factors in the Control of Cyclodimer Distribution

✍ Scribed by Prof. Dr. Paul Heimbach; Dipl.-Chem. Joachim Kluth; Dr. Hartmut Schenkluhn; Dr. Bruno Weimann

• Publisher: John Wiley and Sons
• Year: 1980
• Tongue: English
• Weight: 210 KB
• Volume: 19
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/anie.198005701

✦ Synopsis

optimum polynomial quotient S'/d (S': variance of fit; 2. variance of experimental values). the multicorrelation coefficient M R . and a Chi' test.

[4] C. A. Tolman. Chem. Rev. 77. 313 (1977): the "electronic" parameter x, of the ligand L, is determined by IR spectroscopy ria the induced shlft of the u<o(Al) band of the L,Ni(CO), complex, and the "steric" paramter A, as the Corresponding apical angle.