Ligand-Property Control in the Nickel(0)/Butadiene/P-Ligand Catalytic System: Dominance of “Steric” Factors in the Control of Oligomer Distribution

Ligand-Property Control in the Nickel(0)

Ligand-Property Control in the Nickel(0)/Butadiene/P-Ligand Catalytic System: “Electronic” Factors in the Control of Cyclodimer Distribution

✍ Prof. Dr. Paul Heimbach; Dipl.-Chem. Joachim Kluth; Dr. Hartmut Schenkluhn; Dr. 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 English ⚖ 210 KB

optimum polynomial quotient S'/d (S': variance of fit; 2. variance of experimental values). the multicorrelation coefficient M R . and a Chi' test. [4] C. A. Tolman. Chem. Rev. 77. 313 (1977): the "electronic" parameter x, of the ligand L, is determined by IR spectroscopy ria the induced shlft of t