Ligand Field Theory of Ni(II) Complexes. III. Electronic Spectra and Solution Paramagnetism of Some Diamagnetic Ni(II) Complexes
β Scribed by Maki, Gilda
- Book ID
- 115517710
- Publisher
- American Institute of Physics
- Year
- 1958
- Tongue
- English
- Weight
- 890 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0021-9606
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π SIMILAR VOLUMES
## Abstract The protonation and complex formation of the new ligand 3,3β², 5,5β²βtetramethylβdipyrrometheneβ4,4β²βdicarboxylate in aqueous solutions was investigated by alkalimetric titrations and spectrophotometric measurements (25Β°, I = 1 (KNO~3~)). The p__K__ values for the Nο£ΏH groups are 8.03 and
Polarized optical spectra of three planar low-spin ds complexes, Ni(detc),, NiCl(detc) (PPh,) and Pd(detc), (where detc is diethyldithiocarbamate and PPhl is triphenylphosphine), are reported. The assignments of the spectral transitions were made based on the d-level ordering xyzyz~x2-y2rxz~z2. The