Polarized electronic spectral studies on some diethyldithiocarbamate complexes of Ni(II) and Pd(II)

✍ Scribed by M.V. Rajasekharan; G.V.R. Chandramouli; P.T. Manoharan

• Publisher: Elsevier Science
• Year: 1989
• Tongue: English
• Weight: 480 KB
• Volume: 162
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(89)85076-6

✦ Synopsis

Polarized optical spectra of three planar low-spin ds complexes, Ni(detc),, NiCl(detc) (PPh,) and Pd(detc), (where detc is diethyldithiocarbamate and PPhl is triphenylphosphine), are reported. The assignments of the spectral transitions were made based on the d-level ordering xyzyz~x2-y2rxz~z2. The observed spectral bands in all three complexes are correlated with each other.