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Ligand exchange reactions between copper(II)- and nickel(II)-chelates of different sulfur- and selenium-containing ligands—II

✍ Scribed by W. Dietzsch; J. Lerchner; J. Reinhold; J. Stach; R. Kirmse; G. Steimecke; E. Hoyer

Book ID
115975999
Publisher
Elsevier Science
Year
1980
Weight
688 KB
Volume
42
Category
Article
ISSN
0022-1902

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Ligand exchange reactions between copper
Ligand exchange reactions between copper(II)- and nickel(II)-chelates of different sulfur- and selenium-containing ligands. VI [1]. Kinetics of ligands exchange reactions studied by stopped-flow ESR
✍ J. Stach; R. Kirmse; W. Dietzsch; G. Lassmann; V.K. Belyaeva; I.N. Marov 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 417 KB

enolates) were found to have an equilibrium constant ofK=4. The kinetics of ligand exchange reactions studied by means of stopped-flow ESR measurements are reported. The concentration-time curves recorded for all reactions investigated correspond to simple second-order rate laws. The rate constants