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Ligand exchange reactions between copper(II)- and nickel(II)-chelates of different sulfur- and selenium-containing ligands

✍ Scribed by W. Dietzsch; J. Reinhold; R. Kirmse; E. Hoyer; I.N. Marov; Vera K. Belyaeva

Book ID
115974804
Publisher
Elsevier Science
Year
1977
Weight
616 KB
Volume
39
Category
Article
ISSN
0022-1902

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Ligand exchange reactions between copper
Ligand exchange reactions between copper(II)- and nickel(II)-chelates of different sulfur- and selenium-containing ligands. VI [1]. Kinetics of ligands exchange reactions studied by stopped-flow ESR
✍ J. Stach; R. Kirmse; W. Dietzsch; G. Lassmann; V.K. Belyaeva; I.N. Marov πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science 🌐 English βš– 417 KB

enolates) were found to have an equilibrium constant ofK=4. The kinetics of ligand exchange reactions studied by means of stopped-flow ESR measurements are reported. The concentration-time curves recorded for all reactions investigated correspond to simple second-order rate laws. The rate constants