The asymmetric unit of the title complex, [Ag 6 (C 8 H 6 N 3 ) 6 ], contains one half-molecule; the molecule is centrosymmetric. The Ag atoms form two nearly equilateral triangles, with AgÁ Á ÁAg distances of 3.725 (3), 3.741 (3) and 3.843 (2) A ˚. ## Related literature For general background, se
Ligand Exchange on Pyrazolate-κ N -μ-pyrazolate and Pyrazole-κ N -μ-pyrazolate Binuclear Nickel Complexes
✍ Scribed by Cámpora, Juan; López, Jorge A.; Maya, Celia M.; Palma, Pilar; Carmona, Ernesto; Ruíz, Caridad
- Book ID
- 127007960
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 241 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0276-7333
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📜 SIMILAR VOLUMES
The crystal structure of the title compound, [Cd 2 Cl 4 -(C 6 H 9 N 3 S) 2 ], has been determined. The compound is isomorphous with the previously reported Cu II and Co II complexes. It is centrosymmetric and contains binuclear molecular units with five-coordinate Cd atoms, doubly bridged by Cl atom
The title compound, {(C 10 H 10 N 2 )[Cu 2 (C 5 HN 2 O 4 ) 2 ]} n , has been synthesized under hydrothermal conditions. The self-assembly of the pyrazole-3,5-dicarboxylate ligands and Cu II atoms results in a one-dimensional anionic chain, in which the Cu II atom is five-coordinate in a square-pyram