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Ligand exchange mechanism of fac-[99mTc(CO)3(H2O)3]+ complex for 99mTc-CO-MIBI radiopharmaceuticals

โœ Scribed by Li-Hai Yu; De-Cai Fang; Hui-Ying Ren; Hong-Mei Jia; Bo-Li Liu


Book ID
116799585
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
75 KB
Volume
37
Category
Article
ISSN
0969-8051

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## Abstract __S__โ€Alkylated cysteines are used as efficient tridentate N,O,Sโ€donorโ€atom ligands for the __fac__โ€[M(CO)~3~]^+^ moiety (M=^99m^Tc or Re). Reaction of (Et~4~N)~2~[ReBr~3~(CO)~3~] (3) with the model __S__โ€benzylโ€Lโ€cysteine (2) leads to the formation of [Re(2โ€ฒ)(CO)~3~] (4) as the exclusi